You can access the internalId of list items with GET /lookups/{fieldname}, replacing {fieldname} with the name of a picklist.
The response for GET /lookups/currency looks like this:
[
  {
    "internalId": "1",
    "name": "USA"
  },
  {
    "internalId": "2",
    "name": "British pound"
  },
  {
    "internalId": "3",
    "name": "Canadian dollar"
  },
  {
    "internalId": "4",
    "name": "Euro"
  }
]
